Cold Pressed Orange Oil Data Sheet - Safety Sheet

Product Data Sheet
Preparation Date: 12/26/96

DESCRIPTION

Cold Pressed Orange Oil is the cold pressed volatile oil obtained by expression from peel of the ripe citrus fruit. Midseason Cold Pressed Orange Oil comes from pineapple and seedling varieties of citrus. Valencia Cold Pressed Orange Oil is restricted to the late season Valencia fruit.

APPEARANCE & ODOR

Bright and clear yellow to orange liquid. Midseason tending to have slightly darker color. Characteristic odor of the outer part of the fresh, sweet orange peel.

TYPICAL ANALYSIS

Appearance Light yellow-orange oil
Odor Fresh orange aroma
Specific Gravity (25C) 0.842 - 0.846
Refractive Index (20C) 1.4720-1.4740
Optical Rotation (25C) +94 - +99
Aldehyde, % (as decyl) 1.2 - 2.5
Flashpoint (cc) 118F
Boiling Point 349F
Evaporation Rate Slow
Water Solubility Insoluble
Vapor Density (air=1) Over 1
Vapor Pressure (20C) 2mmHg
Percent Volatile by Volume 98%

Solubility

Benzyl Benzoate Soluble
Glycerine Insoluble
Mineral Oil Soluble
Propylene Glycol Slightly Soluble

USES & APPLICATIONS

Current d-Limonene formulators may find that Cold Pressed Orange Oil is an effective and economic way to add color and extra citrus aroma to their product. Cold Pressed Orange Oil is a food product with a long history of uses in the flavor and fragrance industry. Examples include its use as an ingredient in fruit flavors and floral perfume compositions. Cold Pressed Orange Oil is a common additive to many products requiring citrus flavor because of the sweet and fresh notes of the product.

PACKAGING

Cold Pressed Orange Oil is packaged in epoxy-lined containers as follows:

1-Gallon Pail 7 Pounds Net Weight 3.2 Kilos Net Weight
5-Gallon Pail 35 Pounds Net Weight 16 Kilos Net Weight
55-Gallon Pail 390 Pounds Net Weight 177 Kilos Net Weight

STORAGE & HANDLING

Filled drums should be stored in well ventilated, covered areas at temperatures which should not exceed 70F (21C) for extended periods of time. Air should be excluded from partially filled drums by displacement with Nitrogen or CO2. Citrus oils are subject to oxidation. This process may be inhibited by the addition of antioxidants. Cold Pressed Orange Oil is "winterized" when it is first produced by storing it at freezing temperatures to remove the majority of natural waxes. Although this process is done as thoroughly as possible, trace amounts of waxy solids may remain and settle out of the product when stored for an extended amount of time, particularly in cold temperatures.

Samples and certificates of analysis are available upon request.

The information contained in these formulations is based on data obtained by Florida Chemical Co., Inc. and is considered accurate. No warranty is express or implied regarding the accuracy of these data, the results to be obtained from the use thereof, or that any such use will not infringe any patent. This information is furnished upon the condition the person receiving it shall determine the suitability for the particular purpose.
Cold Pressed Orange Oil Data Sheet - Safety Sheet

Material Safety Data Sheet
Preparation Date: 12/26/96

Emergency Phone Numbers:
Florida Chemical: (863) 294-8483
CHEMTREC 24 Hour Number (800) 424-9300
In Canada, CANUTEC (613) 996-6666

Section I - IDENTIFICATION

Trade Name: Cold Pressed Orange Oil - Midseason & Valencia
CAS Number: 8028-48-6

Section II - HAZARDOUS COMPONENTS

Volatile Ingredients: D-Limonene is the major component (90%) of Midseason and Valencia Orange Oil. These products are a by-product of citrus and entirely of natural origin.

Hazardous Materials Identification System - HMIS:

1 Health Hazard - Mild skin irritant
2 Flammability - Flashpoint above 100F
0 Reactivity - Stable
B Protection - Safety glasses & gloves recommended

Section III - PHYSICAL DATA

Appearance Light yellow-orange oil
Odor Fresh orange aroma
Specific Gravity (25C) 0.842 - 0.846
Refractive Index (20C) 1.4720-1.4740
Optical Rotation (25C) +94 - +99
Aldehyde, % (as decyl) 1.2 - 2.5
Flashpoint (cc) 118F
Boiling Point 349F
Evaporation Rate Slow
Water Solubility Insoluble
Vapor Density (air=1) Over 1
Vapor Pressure (20C) 2mmHg
Percent Volatile by Volume 98%

Section IV - FIRE AND EXPLOSION HAZARD DATA

Flash Point (cc): 118F
Flammable Limits: LEL = Not Available UEL =Not Available
Extinguishing Media: Carbon dioxide, foam or dry chemical
Special Fire Fighting Procedures: SCBA recommended. Smother to exclude air. Do not use water. Handle as an oil fire.
Unusual Fire and Explosive Hazards: Combustible liquid. Keep away from heat, sparks, and open flame.
Incompatibility (Materials to avoid): Strong oxidizing agents.
Hazardous Decomposition Products: Not Available
Hazardous Polymerization: Will not occur
Conditions to Avoid for Polymerization: Not Available
Stability Considerations: Stable
Conditions to Avoid for Stability: Avoid temperatures over 118F

Section V - HEALTH HAZARD DATA

Health Hazards (Acute and Chronic): Product is a moderate irritant, slight allergen, moderate ingestion and slight inhalation hazard under acute local application. Slight allergen under chronic local application.
This Product Contains Carcinogens (NTP, IARC or OSHA): NO
Signs and Symptoms of Exposure: Product may be irritating to the skin, eyes, nose and throat.
Medical Conditions Generally Aggravated by Exposure: Persons with allergies or pre-existing skin conditions should avoid contact with this product.

Emergency & First Aid Procedures
Eyes: Remove contact lenses at once. Flush with water for at least 15 minutes. If irritation persists, seek medical attention.
Skin: Wash affected area with copious amounts of soap and water. If irritation develops, seek medical attention.
Ingestion: Seek medical attention immediately. Do not leave victim unattended.
Inhalation: If symptoms of overexposure are experienced, evacuate to fresh air. If symptoms persist, seek medical attention.

Section VI - SPILL OR LEAK PROCEDURES

Steps to be Taken if Material is Released or Spilled: Use protective gloves to avoid skin contact. Small spills can be wiped up. Large spills should be absorbed by dirt, sand, or other suitable absorbents for disposal. Do not hose spills down drains, sewers, or waterways. Cold Pressed Orange Oil may be toxic to aquatic organisms. Move leaking containers to well ventilated area. No smoking. Eliminate any source of ignition. Minimize inhalation. Use NIOSH approved respiratory protection device. CAUTION: slippery on floor.

Waste Disposal Method: Incinerate or Dispose in Accordance with Local, State, and Federal Regulations. Taking regulations into consideration, waste may be incinerated or handled through EPA spill control plan via land fill or dilution.

Section VII - SPECIAL PROTECTION INFORMATION

Respiratory Protection: Not normally required. If vapor concentration becomes high, use NIOSH approved respirators.
Ventilation: Local exhaust should be adequate. Mechanical ventilation otherwise recommended if necessary.
Skin Protection: Oil resistant gloves.
Eye Protection: Oil resistant goggles.
Other Protective Equipment: Oil resistant apron, emergency eye wash and shower stations.
Appropriate Hygienic Practices: Wash thoroughly after handling. Launder contaminated clothing before re-use.

Section VIII - SPECIAL PRECAUTIONS

Precautions to be Taken in Handling and Storing: Usual precautions for combustible liquids.
Handling and Storage Precautions: Store in sprinklered warehouse. Avoid contact with incompatible chemicals listed in Section IV. Store in tightly sealed, full containers at temperatures below 80F. Partially filled containers should be blanketed with nitrogen.

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Florida Chemical Company, Inc.
351 Winter Haven Blvd, N.E
Winter Haven, FL 33881-9432
863-294-8483
863-294-7783 fax
info@floridachemical.com